Ab initio study of the spin-orbit coupling between the A(1)Sigma(+)(u) and b(3)Pi(u) electronic states of Na-2

作者：Soorkia S; Le Quere F^*; Leonard C; Figgen D

来源：Molecular Physics, 2007, 105(9): 1095-1104.

DOI：10.1080/00268970601161574

• spin-orbit coupling
• wave packet propagation
• dipole moment

Accurate ab initio representations of the ground X-1 Sigma(+)(g) and the excited A(1)Sigma(+)(u) and b(3)Pi(u) electronic states of Na-2 are computed along with the transition dipole moment between X-1 Sigma(+)(g) and A(1)Sigma(+)(u) and the spin-orbit coupling term between A(1)Sigma(+)(u) and b(3)Pi(u). These data are used to simulate an experiment involving these three states to investigate the effect of spin-orbit coupling on the dynamics of a wave packet oscillating on the A(1)Sigma(+)(u) state.

• 出版日期2007
• 单位中国地震局