Stepwise N-H bond formation from N-2-derived iron nitride, imide and amide intermediates to ammonia

作者:MacLeod K Cory; McWilliams Sean F; Mercado Brandon Q; Holland Patrick L
来源:Chemical Science, 2016, 7(9): 5736-5746.
DOI:10.1039/c6sc00423g

摘要

The pathway from N2 to NH3 at low-coordinate iron complexes is shown through crystallographic and spectroscopic characterization of intermediates, including bridging nitride, imide, and amides. Proton-coupled electron transfer plays a key role in the transformations.

  • 出版日期2016