Anthracene photodimerization in a bis-chromophoric hydrogen-bonding receptor

作者：Liang Chih Kai; Desvergne Jean Pierre; Bassani Dario M^*

来源：Photochemical and Photobiological Sciences, 2014, 13(2): 316-323.

DOI：10.1039/c3pp50322d

The photochemistry and photophysics of a bis-anthracenyl hydrogen-bonding receptor (7-(3,5-bis((6-(4-(anthracen-9-yloxy) butanamido)pyridin-2-yl)carbamoyl)phenylhept-6-ynoate, 2) were investigated in a fluid solution. At room temperature, fluorescence and intersystem crossing compete with intramolecular dimerization to form head-to-head and head-to-tail photoproducts, whereas fluorescence is the principal deactivation pathway at low temperature. Time-resolved fluorescence spectroscopy evidences two excimer-like emitting states whose sensitivity to quenching by oxygen is considerably lower than that of intramolecular photodimerization (K-SV = ca. 450 vs. < 100 L mol(-1), respectively). Based on the temperature-dependence and quenching efficiency of photodimerization, a mechanism is proposed in which the ground-state conformation of the tether controls the formation of the HH vs. HT photodimers via a non-emissive intermediate.

• 出版日期2014