Approach to a facile and selective benzyl-protection of carbohydrates based on silyl migration

作者：Wang Wei^*; Li Xiao Liu; Zhang Ping Zhu; Chen Hua

来源：Chinese Journal of Chemistry, 2008, 26(1): 208-212.

DOI：10.1002/cjoc.200890025

• carbohydrate
• methyl alpha-D-glucopyranoside
• selective benzyl-protection
• silyl migration

A convenient and selective benzyl protection of carbohydrates has been investigated on the basis of the silyl migration under the conventional benzylation conditions, developing a facile and short synthesis of methyl 2,3,6-tri-O-benzyl-alpha-D-glucopyranoside.

• 出版日期2008-1
• 单位河北大学