A hydrothermal method to prepare the spherical ZnS and flower-like CdS microcrystallites

作者：Wang Licheng; Chen Luyang; Luo Tao; Qian Yitai^*

来源：Materials Letters, 2006, 60(29-30): 3627-3630.

DOI：10.1016/j.matlet.2006.03.072

• crystal morphology
• X-ray diffraction
• semiconducting materials
• hydrothermal crystal growth

The spherical ZnS and flower-like US microcrystallites are prepared by a convenient hydrothermal process through the reactions of Zn (CH3COO)(2)center dot 2H(2)O or Cd(CH3COO)(2)center dot 2H(2)O with S and NaH2PO2 center dot H2O in aqueous solution at 180 degrees C for 12 h. Powder X-ray diffraction (XRD) is used to confirm the cubic phases of the ZnS and CdS microcrystallites. Their chemical compositions are characterized by X-ray photoelectron spectroscopy (XPS). Scanning electron microscope (SEM) images show the morphologies of the as-synthesized ZnS and CdS. The photoluminescence spectra (PL) exhibit their optical properties.

• 出版日期2006-12
• 单位中国科学技术大学