Perylene monoanhydride diester: a versatile intermediate for the synthesis of unsymmetrically substituted perylene tetracarboxylic derivatives

作者：Xue Chenming; Sun Runkun; Annab Rana; Abadi Douha; Jin Shi^*

来源：Tetrahedron Letters, 2009, 50(8): 853-856.

DOI：10.1016/j.tetlet.2008.11.084

A Soluble perylene monoanhydride diester has been designed and synthesized. It was successfully utilized as an efficient intermediate for the synthesis of the first unsymmetric perylene tetracarboxylic tetraester and a series of unsymmetric perylene diester monoimides in good to excellent yields. Its application in synthesis of unsymmetric perylene diimides was also demonstrated. Availability of such a versatile intermediate would enable the convenient integration of perylene tetracarboxylic tetraesters and perylene biester monoimides into intricate functional molecular systems.

• 出版日期2009-2-25