科研之友
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摘要
Diastereoselective sulfur oxidation in 2-thio-3-chloroacrylamides is described A range of chiral amine auxiliaries was incorporated in the beta-chloroacrylamide, and the efficiency with which the stereochemistry was relayed to the sulfur centre during sulfoxidation was investigated. Diastereomeric ratios of up to 3 3 1 were achieved.
- 出版日期2010-4-21
