科研之友
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摘要
The isolation of binary As-N and ternary As-N-P cage compounds consisting exclusively of group 15 elements was achieved by exploiting the reactivity of diarsadiazanediyl. This arsenic centered biradical is capable of activating and/or quenching small molecules bearing double bonds such as diazenes, Ph-N=N-Ph, or in situ generated labile diphosphenes, e.g. Ph-P=P-Ph, leading to the formation of hexapnicta-[2.1.1]bicyclohexanes.
- 出版日期2018-4-23
