A general synthesis of phosphaalkenes at zirconium with liberation of phosphaformamides

作者:Roering Andrew J; Elrod L Taylor; Pagano Justin K; Guillot Sarah L; Chan Stephanie M; Tanski Joseph M; Waterman Rory*
来源:Dalton Transactions, 2013, 42(4): 1159-1167.
DOI:10.1039/c2dt32322b

摘要

A general, atom-economical method for the synthesis of phosphaalkenes is reported via the net coupling of primary alkyl or aryl phosphines with aryl or alkyl isocyanides at zirconium. The phosphorus-containing ligand can be liberated as the phosphaformamide from zirconium by reaction with an organic electrophile.

  • 出版日期2013