SiO2-like film deposition by dielectric barrier discharge plasma gun at ambient temperature under an atmospheric pressure

作者:Chen Qiang*; Zhang Yuefei; Han Erli; Ge Yuanjing
来源:Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films , 2006, 24(6): 2082-2086.
DOI:10.1116/1.2348724

摘要

A medium-frequency dielectric barrier discharge (DBD) plasma gun was used to deposit SiO2-like films at ambient temperature under atmospheric pressure. SiO2-like films were deposited on Si and stainless-steel surfaces by flowing Ar gas containing hexamethyldisiloxane (HMDSO) monomer through the gun. The authors found that the chemical structure of the deposited SiO2-like film strongly depended on the HMDSO monomer ratio in the flowing gas and on the incident power. Fourier transform infrared spectroscopy showed no hydroxyl group in the chemical structure under the low HMDSO ratio in flowing gas or high incident plasma power. Scanning electron microscopy and atomic force microscopy revealed that SiO2-like films began to grow as islands and then formed in columns having porosity. Oxygen added to the plasma-gun flow plays a lesser role in the SiO2-like deposition from a DBD plasma gun at atmospheric pressure, and the critical temperature for pure SiO2 formation is also greatly lowered.

  • 出版日期2006-12
  • 单位北京印刷学院