A divalent cadmium coordination polymer featuring a complex tetranodal 3-D topology and hexadecameric water clusters

作者：Nettleman Joseph H; Sposato Laura K; LaDuca Robert L^*

来源：Inorganic Chemistry Communications, 2011, 14(5): 711-714.

DOI：10.1016/j.inoche.2011.02.013

• Coordination polymer
• Cadmium
• Crystal structure
• Water cluster
• Hydrogen bonding
• Luminescence

The luminescent coordination polymer {[Cd-2(dms)(2)(bpmp)(1.5)]center dot 8H(2)O}(n) (1, dms=2,2-dimethylsuccinate, bpmp=bis(4-pyridylmethyl)piperazine) exhibits [Cd-2(dms)(2)(bpmp)](n) layers partially pillared by other crystallographically distinct bpmp ligands into a complex 3-D 3,4,5-connected tetranodal network. Hydrogen-bonded hexadecameric water molecule clusters lie in incipient channels.

• 出版日期2011-5