Acid hydrolysis of amines and cleavage of 1,3,7-triazapyrene ethers

作者:Saigakova N A*; Demidov O P; Borovlev I V
来源:Russian Journal of Organic Chemistry, 2013, 49(8): 1199-1202.
DOI:10.1134/S1070428013080174

摘要

Acid hydrolysis of 6-amino derivatives of 1,3,7-triazapyrene affords the corresponding 6-oxo-6,7-dihydro-1,3,7-triazapyrenes. In the case of 6,8-bis(dialkylamino)-1,3,7-triazapyrenes depending on their structure products of hydrolysis of one or two dialkylamino groups are obtained. 6-Alkoxy-8-dialkylamino-1,3,7-triazapyrenes were synthesized. Conditions were found providing a possibility to cleave an ether bonds in the presence of amino group in the 1,3,7-triazapyrene structure and also to perform the hydrolytic substitution of both functional groups.

  • 出版日期2013-8