Anion detection driven by a surprising internal hydrogen-bonding association in a dinuclear Rhenium(I) complex

作者:Pelleteret Diane; Fletcher Nicholas C*; Doherty Andrew P
来源:Inorganic Chemistry, 2007, 46(11): 4386-4388.
DOI:10.1021/ic700452k

摘要

A neutral dinuclear rhenium(I) bipyridinetricarbonyl bromide complex has been investigated with a range of anions, giving a remarkable binding affinity for dihydrogenphosphate. These studies highlight that anion sensing can be achieved with structurally simple species provided that the compound adopts an unconventional conformation, through, for example, intramolecular hydrogen bonding in solution.

  • 出版日期2007-5-28