Nanoparticulate palladium catalyst stabilized by supported on feather keratin for Suzuki coupling reaction

作者:Ma Hengchang*; Bao Zhikang; Han Guobin; Yang Ningning; Xu Yufei; Yang Zengming; Cao Wei; Ma Yuan
来源:Chinese Journal of Catalysis, 2013, 34(3): 578-584.
DOI:10.1016/S1872-2067(11)60472-5

摘要

Palladium nanoparticles supported in a feather keratin matrix were efficient catalyst for the coupling reactions of aryl bromides with arylboronic acid in aqueous medium under mild reaction conditions. The biopolymer-based catalyst demonstrated excellent activity for substrates with a wide range of functional groups. The product biaryls were precipitated from the reaction mixture with good to excellent yields and purities. The catalyst was recovered from the reaction solution easily by simple filtration, and can be reused at least seven times.