Promoting effect of synthesis method on the property of nickel oxide doped CeO2-ZrO2 and the catalytic behaviour of Pd-only three-way catalyst

作者：Li Guangfeng; Wang Qiuyan; Zhao Bo; Zhou Renxian^*

来源：Applied Catalysis B: Environmental , 2011, 105(1-2): 151-162.

DOI：10.1016/j.apcatb.2011.04.006

• CeO2-ZrO2
• Oxygen storage capacity
• Supercritical drying
• Pd-only three-way catalysts

CeO2-ZrO2 doped by nickel oxide (CZN) with different method and Pd-only three-way catalysts (Pd/CZN) were prepared and characterized. The catalyst prepared by co-precipitation and supercritical drying process (Pd/CZN-s) exhibits the best catalytic activity and the widest operation working window before and after aging. Compared with other samples. CZN-s shows the formation of more homogeneous ternary solid solution with the smallest lattice parameter and crystallite size. Moreover. CZN-s maintains the high thermal and structural stability with higher surface area and larger pore volume after aging. Pd/CZN-s exhibits higher relative concentration of Ce3+ associated with the formation of more oxygen vacancies before and after aging, confirmed by X-ray photoelectron spectroscopy and Raman results. The more concentration of Ce3+ or oxygen vacancies leads to the enhancement of oxygen storage complete capacity of CZN-s. Moreover, the higher the oxygen storage capacity, the wider the working ranges of air/fuel variations.

• 出版日期2011-6-9
• 单位台州学院; 浙江大学