Uniform magnetization reversal in dual main-phase (Ce,Nd)2Fe14B sintered magnets with inhomogeneous microstructure

作者:Zhang, Le-le*; Li, Zhu-bai; Zhang, Xue-feng; Ma, Qiang; Liu, Yan-li; Li, Yong-feng; Zhao, Qian
来源:Journal of Physics D: Applied Physics , 2017, 50(6): 065001.
DOI:10.1088/1361-6463/aa5361

摘要

The element distribution and the magnetic properties were investigated in (Ce,Nd)-Fe-B sintered magnets prepared by mixing Nd13.5Fe80B6.5 and Ce9Nd4.5Fe80B6.5 powders with different mass ratios. Two main phases exist, but element diffusion is evident, and the chemical composition of the main phase is widely different from that of the master alloy. The Ce element tends to be expelled from the Ce-rich Re2Fe14B phase. Compared with the Ce-rich main phase, the Nd-rich Re2Fe14B phase is more stable in structure. Although the microstructure is inhomogeneous and the magnetocrystalline anisotropy is variable, the magnetization reversal is uniform in these dual main-phase magnets, which should ascribe to the existence of the exchange coupling, and magnetization reversal undergoes the nucleation of the reversed domain in irreversible magnetization. It is expected to further improve the coercivity by optimizing the distribution of the Nd-rich main phase in preparing the resource-saving (Ce,Nd)(2)Fe14B sintered magnets.