2D water layer enclathrated between Mn(II)-Ni(CN)(4) coordination frameworks

作者：Ray Ambarish; Bhowmick Indrani; Sheldrick William S; Jana Atish Dipankar^*; Ali Mahammed

来源：Journal of Solid State Chemistry, 2009, 182(10): 2608-2612.

DOI：10.1016/j.jssc.2009.05.014

• 2D coordination polymer
• 2D ice layer
• Boat-shaped hexagonal water clusters
• Reversible water adsorption
• High thermal stability

A [Ni(CN)(4)](2-)-based two-dimensional Mn(II) coordination polymer {Mn(H2O)(2)[NiCN](4) center dot 4H(2)O}, in which the coordination layers are stacked on top of each other sandwiching 2D water layer of boat-shaped hexagonal water clusters has been synthesized. The complex exhibits high thermal decomposition temperature and reversible water absorption, which were clearly demonstrated by thermal and PXRD studies on the parent and rehydrated complex after dehydration.

• 出版日期2009-10