Amino- and hydroxymethylation of hydride adducts of 2-hydroxy-3,5-dinitropyridine

作者：Ivanova E V; Fedyanin I V; Surova I I; Blokhin I V; Atroshchenko Yu M^*; Shahkeldyan I V

来源：Chemistry of Heterocyclic Compounds, 2013, 49(7): 1000-1008.

DOI：10.1007/s10593-013-1338-6

• 3,7-diazabicyclo[3.3.1]nonanes
• 2-hydroxy-3,5-dinitropyridine
• Mannich reaction

A series of 1,5-dinitro-3,3-diazabicyclo[3.3.1]nonan-2-one derivatives has been synthesized by Mannich condensation of the hydride adduct of 2-hydroxy-3,5-dinitropyridine with formaldehyde and primary amines. The structure of the obtained compounds was proved by NMR spectroscopy.

• 出版日期2013-10