SO2 Removal and Regeneration of MgO-Based Sorbents Promoted with Titanium Oxide

作者:Lee Soo Jae; Jung Suk Yong; Lee Soo Chool; Jun Hee Kwon; Ryu Chong Kul; Kim Jae Chang*
来源:Industrial & Engineering Chemistry Research, 2009, 48(5): 2691-2696.
DOI:10.1021/ie801081u

摘要

To improve the deactivation of the sorbent for the removal Of SO2 in residue fluid catalytic cracking plants, a Ce-Fe-MgO sorbent with excellent sulfur removal capacity and regeneration ability was modified by adding new promoters such as Ti, Al, and Zr. The sorbents were prepared by a coprecipitation method, and their sulfur removal capacities and regeneration abilities were measured in a fixed-bed reactor during multiple cycles. In particular, the sulfur removal capacity of the CeFeMgTi sorbent showed a high absorption value (41.2 g of sulfur/g of absorbent x 100) and excellent regeneration ability during multiple cycles. These results can be explained by the difference in their crystal structures and the physical and textural properties.

  • 出版日期2009-3-4