An inorganic-organic hybrid framework from the assembly of an electron-rich diphosphonate and electron-deficient tripyridyl moiety

作者：Ma, Yu-Juan; Han, Song-De; Pan, Jie; Mu, Ying; Li, Jin-Hua; Wang, Guo-Ming^*

来源：Journal of Materials Chemistry C, 2018, 6(35): 9341-9344.

DOI：10.1039/c8tc02903b

• INDUCED PHOTOCHROMIC MATERIAL
• ROOM-TEMPERATURE
• IN-SITU
• METAL
• PHOSPHATE
• LIGANDS
• FLUORESCENT
• COMPLEX
• CAGE

The combination of an electron-rich zinc diphosphonate layer and electron-deficient 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPT) generates a 3D inorganic-organic hybrid with an [-ED-EA-ED-EA-] arrangement (ED = electron donor and EA = electron acceptor), which exhibits a wide and rapid photoresponse upon exposure to the stimulus of sunlight, UV light and X-rays at ambient temperature. Notably, the coloration time is 0.1 s when exposed to UV light (320 nm) generated from a Xe-lamp (150 W).

• 出版日期2018-9-21
• 单位青岛大学