The chlorination kinetics of zirconium dioxide mixed with carbon black

作者：Movahedian A; Raygan Sh^*; Pourabdoli M

来源：Thermochimica Acta, 2011, 512(1-2): 93-97.

DOI：10.1016/j.tca.2010.09.006

• Carbochlorination
• Zirconia
• Temperature
• Briquette
• Activation energy
• Solid-gas reaction models
• Thermogravimetric analysis
• Kinetics

In this research, the effects of chlorine gas at different chlorine partial pressures and carbon concentrations on the carbochlorination of zirconia were studied. It was found that in briquettes containing 18.7 %wt carbon, in a chlorine partial pressure range of 0.25-0.75 atm and for a reacted fraction of less than 0.7, the chemical reaction model was dominant for the carbochlorination process of zirconia. The order of reaction into chlorine gas (n) in this situation was 0.57. Moreover, the best weight ratio of carbon to zirconia was 40/60. In this case, the activation energy of the reaction was 209.9 kJ mol(-1) in a temperature range of 1023-1223 K, and the dominant model was the chemical reaction model.

• 出版日期2011-1-10