Artifact-free measurement of residual dipolar couplings in DMSO by the use of cross-linked perdeuterated poly(acrylonitrile) as alignment medium

作者：Kummerloewe Grit; Behl Marc; Lendlein Andreas; Luy Burkhard^*

来源：Chemical Communications, 2010, 46(43): 8273-8275.

DOI：10.1039/c0cc02730h

Perdeuterated poly(acrylonitrile) is introduced as a practically proton-free alignment medium for the measurement of anisotropic NMR parameters; its use in conventional glass tubes and in a Kalrez (R) 8002 UP-based stretching device with resulting spectra of astonishing quality are demonstrated.

• 出版日期2010