A new (4,6)-connected Cu(I) coordination polymer based on rare tetranuclear [Cu4I2] clusters: Synthesis, crystal structure, luminescent and photocatalytic properties

作者：Cui, Li-Jing; Liu, Chun-Yan; Bian, Ming; Yu, Li-Jun^*

来源：Journal of Molecular Structure, 2018, 1155: 7-10.

DOI：10.1016/j.molstruc.2017.10.108

• Cu(l) compound
• Solvothermal synthesis
• Luminescence
• Photocatalytic activity

A new Cu(I) coordination polymer, namely [Cu5I3(L)(2)](n) (1 HL = 3-(4-pyridy1)-5-(3-pyridy1)-1,2,4-triazolyl), was solvothermally synthesized using Cu!, HL and NaI as the starting materials. Single crystal X-ray structural analysis shows that compound 1 features a (4, 6)-connected 3D framework employing rare tetranuclear [Cu4I2] clusters as building subunits. It exhibits intense metal-to-ligand luminescence and excellent photocatalytic activity on degradation of methylene blue (MB).

• 出版日期2018-3-5
• 单位内蒙古民族大学; 广东食品药品职业学院