Assembly of [(Mn2Mn2III)-Mn-II] S=9 Clusters via Azido Bridges: a New Single-Chain Magnet

作者:Escuer Albert*; Vlahopoulou Gina; Mautner Franz A
来源:Inorganic Chemistry, 2011, 50(7): 2717-2719.
DOI:10.1021/ic102391e

摘要

In the present work, we report a new manganese single-chain magnet built from tetranuclear (Mn2Mn2III)-Mn-II mixed-valence units linked by end-on azido and oximato bridges. All of the intra- and intercluster interactions involve end-on azido bridges, resulting in one ferromagnetic chain of ferromagnetic clusters with local ground state S = 9.

  • 出版日期2011-4-4