Size-Controllable Synthesis of Fe3O4 Nanospheres for Electromagnetic Wave Absorber

作者：Wang, Yanping; Sun, Danping; Liu, Gongzong; Wang, Yujiao; Jiang, Wei^*

来源：Journal of Electronic Materials, 2015, 44(7): 2292-2299.

DOI：10.1007/s11664-015-3725-5

• NANOPARTICLES
• GRAPHENE

We present a hydrothermal method to control the size of Fe3O4 nanospheres by adjusting the concentration of FeCl3 center dot 6H(2)O in ethylene glycol/diethylene glycol binary solvent mixtures. The electromagnetic wave absorption properties of Fe3O4 nanospheres of different diameters have been investigated using a vector network analyzer. The reflection loss of Fe3O4 nanospheres/paraffin wax composite can reach as high as -30.00 dB at 17.50 GHz and -37.95 dB at 7.67 GHz for Fe3O4 nanospheres with diameter of about 120 nm and 170 nm, respectively. The absorption bandwidth with reflection loss below -10 dB is up to 7.01 GHz when the Fe3O4 diameter is about 220 nm. In contrast, the bandwidth decreased to 4.28 GHz when the size shrank to 70 nm. Therefore, our method can be utilized to precisely control the size of Fe3O4 nanospheres in order to manipulate their electromagnetic wave absorption properties.

• 出版日期2015-7
• 单位南京理工大学