科研之友
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摘要
The oxidation chemistry of nitrous oxide (N2O) includes a wide range of both catalytic and non-catalytic selective oxidation reactions. This review summarizes the results of modern experimental and theoretical studies devoted to non-catalytic oxidation reactions of N2O with carbon-carbon double bonds of alkenes and polymers. It is shown that these reactions open up a promising way for the synthesis of diverse carbonyl compounds (ketones and aldehydes) as well as a new type of functionalized oligomers-unsaturated polyketones. Possible applications of unsaturated polyketones, as well as economic aspects of N2O production and use as a selective oxidant are discussed. The bibliography includes 109 references.
- 出版日期2017
