摘要

A novel microporous organic polymer framework with built-in metal sites in the skeleton has been synthesized by the Sonogashira-Hagihara reaction using salen-palladium as building units. The new microporous organic polymer possesses a high BET surface area, large pore volume, good stability and acts as a highly efficient robust recyclable heterogeneous catalyst towards carbon-carbon coupling reactions with low catalyst loading.

  • 出版日期2013
  • 单位超分子结构与材料国家重点实验室; 吉林大学; 集成光电子学国家重点实验室