Azobenzamide-based proteomorphous objects as a light/pH-induced photoswitchable module

作者:Yadav Promod Kumar; Singh Alok Kumar; Kumar Anup; Kumari Niraj; Gulino Antonino; Mishra Lallan*; Gupta Tarkeshwar
来源:RSC Advances, 2014, 4(14): 7174-7177.
DOI:10.1039/c3ra43576h

摘要

Azobenzamide-based molecular scaffolds viz. (E)-4,4%26apos;(diazene-1,2-diyl)bis(N-pyridin-3-yl)benzamide (1) and (E)-4,40(diazene-1,2-diyl)bis(N-pyridin-4-yl) benzamide (2), yield proteomorphous architectures i.e., secondary %26quot;beta-pleated sheet%26quot; and tertiary %26quot;beta-hairpin%26quot; respectively, that offer %26quot;optical data storage%26quot; competence as a result of reversible light-induced conformational changes in organic solvent.

  • 出版日期2014