摘要

It has been established that a cationic gold(I)/axially chiral biaryl bisphosphine complex catalyzes asymmetric dearomatization of 1-aminonaphthalene derivatives by the intramolecular double C-C bond formation. Two different dearomatization products were obtained depending on the substituents on the benzyl groups at the alkyne termini.

  • 出版日期2015-2-6