A novel one-pot synthesis of secondary alcohols from esters

作者：Chae Min Jung; Jeon Ah Ram; Park Jae Kyo; An Duk Keun^*

来源：Tetrahedron Letters, 2011, 52(14): 1718-1720.

DOI：10.1016/j.tetlet.2011.02.005

Alkylation or vinylation by using organometallic reagents after partial reduction of carboxylic esters with LDBBA gave secondary alcohols, also involving allyl alcohols, without any isolation of intermediates in good yield (54-78%).

• 出版日期2011-4-6