科研之友
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摘要
A symmetrical alpha,omega-diene monomer with a 36 methylene run length was synthesized and polymerized, and the unsaturated polymer was hydrogenated to generate precision polyethylene possessing a butyl branch on every 75th carbon (74 methylenes between branch points). The precision polymer sharply melts at 104 degrees C and exhibits the typical orthorhombic unit cell structure with two characteristic wide-angle X-ray diffraction (WAXD) crystalline peaks observed at 21.5 degrees and 24.0 degrees, corresponding to reflection planes (110) and (200), respectively.
- 出版日期2011-8-10
