Dy(III) zig-zag chains assembled in a 3D framework with single-molecule magnet behaviour

作者:Bai, Chao; Li, Chuan-Ti; Hu, Huai-Ming*; Liu, Bin; Li, Jin-Dian; Xue, Ganglin
来源:Dalton Transactions, 2019, 48(3): 814-817.
DOI:10.1039/c8dt03617a

摘要

A new lanthanide-based framework, [Dy(STP)(1,2-bdc)](n) (1), was constructed. It represents dysprosium(III) 1D zigzag chains in a 3D framework and displays single-molecule magnet (SMM) behaviour with an energy barrier of 55.76 K under zero dc field.