A four-fold interpenetrated metal-organic framework as a fluorescent sensor for volatile organic compounds

作者：Zhao, Xiaoyu; Li, Yang; Chang, Ze^*; Chen, Long^*; Bu, Xian-He

来源：Dalton Transactions, 2016, 45(38): 14888-14892.

DOI：10.1039/c6dt02169g

• AGGREGATION-INDUCED EMISSION
• TURN-ON FLUORESCENCE
• COORDINATION POLYMERS
• LUMINESCENT SENSOR
• AQUEOUS-SOLUTION
• CARBON-DIOXIDE
• MOLECULES
• LIGAND
• MOF
• TEMPERATURE

A four-fold interpenetrated three dimensional (3D) metal-organic framework, [Cd-2(tppe)(bpdc)(2)(H2O)]center dot solvent (1), was synthesized with a tetraphenylethene (TPE)-based ligand, 1,1,2,2-tetrakis(4-(pyridin-4-yl) phenyl) ethene (TPPE). This complex exhibits intense blue luminescence and is sensitive to toxic volatile organic compounds (VOCs).

• 出版日期2016
• 单位南开大学; 天津大学