A three-dimensional accordion-like metal organic framework: synthesis and unconventional oriented growth on a surface

作者：Haraguchi Tomoyuki; Otsubo Kazuya; Sakata Osami; Kawaguchi Shogo; Fujiwara Akihiko; Kitagawa Hiroshi

来源：Chemical communications, 2016, 52(35): 6017-6020.

DOI：10.1039/c6cc00056h

We describe the synthesis and sorption properties of a new metal organic framework (MOF), Fe(H2O)(2)(bpy)[Pt(CN)(4)]center dot H2O (bpy = 4,4'-bipyridine), with a three-dimensional accordion-like structure. Although crystalline oriented MOF thin films reported to date have been mainly limited to a layer-type structure, we succeeded in the fabrication of its crystalline oriented thin film.

• 出版日期2016