Adsorbed molecules in external fields: Effect of confining potential

作者：Tyagi Ashish^*; Silotia Poonam; Maan Anjali; Prasad Vinod

来源：Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy , 2016, 169: 238-245.

DOI：10.1016/j.saa.2016.04.052

• Orientation
• Alignment
• Hindered rotor
• Molecule-surface interaction
• confining potential

We study the rotational excitation of a molecule adsorbed on a surface. As is well known the interaction potential between the surface and the molecule can be modeled in number of ways, depending on the molecular structure and the geometry under which the molecule is being adsorbed by the surface. We explore the effect of change of confining potential on the excitation, which is largely controlled by the static electric fields and continuous wave laser fields. We focus on dipolar molecules and hence we restrict ourselves to the first order interaction in field molecule interaction potential either through permanent dipole moment or/and the molecular polarizability parameter. It is shown that confining potential shapes, strength of the confinement, strongly affect the excitation. We compare our results for different confining potentials.

• 出版日期2016-12-5