Graphene oxide improved thermal and mechanical properties of electrospun methyl stearate/polyacrylonitrile form-stable phase change composite nanofibers

作者：Ke, Huizhen; Pang, Zengyuan; Xu, Yunfei; Chen, Xiaodong; Fu, Jiapeng; Cai, Yibing; Huang, Fenglin; Wei, Qufu^*

来源：Journal of Thermal Analysis and Calorimetry, 2014, 117(1): 109-122.

DOI：10.1007/s10973-014-3669-7

• Form-stable PCMs
• Graphene oxide
• Polyacrylonitrile
• Methyl stearate
• Mechanical properties
• Thermal conductivity

In the present work, a novel PAN-based form-stable composite phase change materials with the methyl stearate (MES) encapsulated in the supporting matrices of polyacrylonitrile (PAN) nanofibers were fabricated through electrospunning for the storage and retrieval of thermal energy. Influences of graphene oxide (GO) addition on the chemical properties, structural morphologies, mechanical properties, thermal energy storage properties, thermal stability, and thermal energy storage/retrieval rates of electrospun MES/PAN/GO phase change composite nanofibers were systematically investigated by FT-IR, FE-SEM, tensile testing, DSC, TG, and measurement of melting/freezing times, respectively. The results revealed that the incorporation of GO effectively enhanced the mechanical properties, thermal stability, as well as heat storage and release rates of the phase change composite nanofibers. The averaged tensile strength of electrospun MES/PAN/GO phase change composite nanofibers increased significantly by 573 % with 10 mass% loading of GO, while elongation at break had a maximum 107 % increment when adding 3 mass% of GO. The DSC results indicated that the electrospun PAN-based phase change composite nanofibers with various GO loadings had suitable phase transition temperatures with the latent heat ranging from about 92 to 109 kJ kg(-1) and exhibited good thermal reliability in terms of DSC measurements during 50 melting-freezing cycles. Moreover, the melting and freezing time were significantly decreased about 44 and 43 % for the MES/PAN/GO5, as well as 59 and 64 % for the MES/PAN/GO10 after introducing the GO into the composite nanofibers systems.

• 出版日期2014-7
• 单位江南大学