A novel "turn-on'' fluorescent probe for Fe3+ in aqueous media based on C=N isomerization

作者:Xu Huajie; Liu Zhaodi*; Sheng Liangquan; Chen Mingming; Huang Deqian; Zhang Hong; Song Chongfu; Chen Shuisheng
来源:New Journal of Chemistry, 2013, 37(2): 274-277.
DOI:10.1039/c2nj40767a

摘要

A new type of fluorescent probe (L) for Fe3+ based on C=N isomerization was synthesized. It shows fluorescence enhancement (turn-on) response for Fe3+ in aqueous media (v(CH3CN) : v(H2O) = 1:9). The complexation mode and the corresponding fluorescent enhancement mechanism were elucidated by IR spectra, transient spectra, Job plot, and DFT calculations.