A 2-Fold Interpenetrated Framework Assembled from Pyridine-3-carboxylate Ligand and Transition Metal: Synthesis, Structure and Photoluminescent Property

作者：Wang Kuai-Bing; Wang Yan; Chen You-Cun^*

来源：Chinese Journal of Structural Chemistry, 2009, 28(5): 590-596.

• self-assembly
• cadmium(II) complex
• interpenetration
• luminescence

A novel cadmium(U) coordination polymer [Cd-2(3-pa)4(4,4'-bpy)(H2O)]center dot 3.08H(2)O 1 has been synthesized by pyridine-3-carboxylate (3-paH) and CdO with exo-bidentate rigid dipyridyl ligand 4,4'-bipyridine (4,4'-bpy) by using a hydrothermal method, its structure was determined by single-crystal X-ray diffraction and its luminescent property was also documented. Complex 1 crystallizes in orthorhombic space group Pbcn with a = 21.4074(14), b = 27.1119(18), c = 12.3879(8) angstrom, V = 7189.9(8) angstrom(3), Z = 8, C34H32.16Cd2N6O12.08, M-r = 942.85, D-c = 1.742 g/cm(3), mu = 1.255 mm(-1) and F(000) = 3766. The structure was solved by direct methods and refined to R = 0.0353 and wR = 0.0891 for 6278 observed reflections (I > 2 sigma(I)). The most prominent structural feature is the mutual interpenetration of two identical 3-D open frameworks via filling the large void space, which gives a 2-fold interpenetrating architecture during the self-assembly process.

• 出版日期2009
• 单位安庆师范大学