Aqueous radical addition-coupling polymerization using a nitroso benzene/cyclodextrin complex for the synthesis of a hydrophilic periodic polymer

作者：Tao, Fangqi; Wang, Qi^*

来源：RSC Advances, 2015, 5(57): 46007-46010.

DOI：10.1039/c5ra02371h

• ALPHA-CYCLODEXTRIN
• METAL-COMPLEXES
• SEQUENCE
• COPOLYMERS
• MONOMER
• INCLUSION
• CHEMISTRY
• RACP

A hydrophilic periodic polymer possessing a [AB(x)AC](n) (A - ester, B - ethylene oxide, C - N-O) repeating sequence was synthesized by aqueous radical addition-coupling polymerization using a water-soluble inclusion complex of nitrosobenzene and Me-2-beta-cyclodextrin together with poly(ethylene glycol) bis(alpha-bromoisobutyrate) in the presence of Cu/ligand.

• 出版日期2015
• 单位浙江大学