Phenyl Substituted Porphyrins. 6. Acylation of Alcohols with Carboxyphenylporphyrins

作者：Salnikova Mariya A; Lubimova Tatiana V; Syrbu Sergei A; Semeikin Alexander S^*

来源：Macroheterocycles, 2016, 9(2): 141-150.

DOI：10.6060/mhc151086s

• Porphyrins
• acylation
• perfluorinated alcohols
• 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride (EDAC)
• 4-dimethylaminopyridine (DMAP)

Pyrrolic precursors and benzaldehydes were used to afford meso-carboxyphenylporphyrins bearing one or four carboxyl groups. The reaction conditions for the acylation of alcohols with the obtained carboxyphenylporphyrins in the presence of carbodiimides were studied. Optimal reaction conditions were found and a series of phenylporphyrin esters of various structure was synthesized.

• 出版日期2016