A Facile Atom-Economic Synthesis of Imidazoles with Chalcogenophosphoryl Substituents via Free-Radical Addition of Secondary Phosphine Chalcogenides to 1-Vinylimidazoles

作者：Gusarova Nina K; Malysheva Svetlana F; Belogorlova Nataliya A; Parshina Lidiya N; Trofimov Boris A^*

来源：Synthesis, 2011, (11): 1777-1782.

DOI：10.1055/s-0030-1260025

• 1-vinylimidazoles
• phosphine sulfides
• phosphine selenides
• radical addition

Secondary phosphine sulfides and selenides react with 1-vinylimidazoles under radical initiation conditions to give the corresponding anti-Markovnikov adducts in up to 98% yields.

• 出版日期2011-6