Activated carbons from acrylic textile waste

作者：Nahil Mohamad Anas; Williams Paul T^*

来源：Journal of Analytical and Applied Pyrolysis, 2010, 89(1): 51-59.

DOI：10.1016/j.jaap.2010.05.005

• Pyrolysis
• Textile waste
• Activated carbon
• Fuels

Acrylic textile waste was pyrolysed in static bed reactor in a nitrogen atmosphere in relation to different pyrolysis temperatures between 500 degrees C and 900 degrees C. Steam activation of the chars generated at 800 degrees C and 900 C was carried out at three different temperatures, 800 degrees C, 850 degrees C and 900 degrees C to produce activated carbons. The chemical transformations of raw material and chars produced were investigated using FTIR. The FTIR spectra indicate the formation of condensed aromatic rings with nitrogen at high temperature. The pyrolysis chars and activated carbons were characterised in relation to process conditions via BET surface area, proximate and elemental analysis and surface characteristics using scanning and transmission electron microscopy. The BET surface area of the pyrolysis chars was all less than 2 m(2) g(-1), but increased with steam activation to produce a maximum surface area of 619 m(2) g(-1) for the activated carbon produced from the char generated at 800 degrees C and steam activated at 900 degrees C. The temperature of steam activation influenced the surface areas of the product activated carbon in that activated carbons produced from chars generated at 800 degrees C were significantly higher than those produced from chars generated at 900 degrees C. Nitrogen adsorption-desorption isotherms, micropore volume, OFT pore size distribution and electron microscopy showed that the activated carbons were mostly microporous.

• 出版日期2010-9