A NEW FLUORESCENCE CHEMOSENSOR FOR Hg2+ BASED ON CARBAZOLE AND THIOUREA

作者:Yin, Fang-fang; Zhu, Wei-ju; Fang, Min; Wu, Zhen-yu; Xu, Ying; Wang, Hai-lun; Wang, Yao; Li, Cun*
来源:Heterocycles, 2017, 94(9): 1719-1727.
DOI:10.3987/com-15-13242

摘要

A new thiourea-based Schiff-base (L) as a fluorescent chemosensor has been designed and synthesized, which exhibits selectivity toward Hg2+ by forming a 1:2 compound based on the method of Job's plot. The detection limit was calculated to be 6.5x10(-6) mol/L. The prominent recognizable changes of could be observed by the naked eyes and fluorescence sensing conditions. The color of the L solution changed instantly from colorless to yellow after adding Hg2+ and returned to colorless by adding I-. The coordination reaction was reversible.

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