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摘要
A regioselective nitration of BN-substituted arene compounds has been successfully developed. The first examples of BN-nitroarenes have been synthesized and structurally characterized by X-ray diffraction analysis. Photophysical studies of these novel compounds reveal an effective pi conjugation between the nitro group and 1,2-azaborine moiety in the solution phase. A plausible mechanism for this nitration reaction is proposed.
- 出版日期2017-5-8
- 单位同济大学
