A versatile and highly efficient post-functionalization method for grafting organic molecules onto Anderson-type polyoxometalates

作者:Vanhaecht Stef; Jacobs Jeroen; Van Meervelt Luc; Parac Vogt Tatjana N*
来源:Dalton Transactions, 2015, 44(44): 19059-19062.
DOI:10.1039/c5dt03559g

摘要

A new azide functionalized Anderson polyoxometalate was synthesized, fully characterized and subsequently used as a building block for further POM post-functionalization with organic compounds through a copper catalyzed azide-alkyne cycloaddition (CuAAC) reaction. Optimization of the reaction conditions led to an efficient, fast, convenient and versatile POM coupling method.

  • 出版日期2015