Decatungstate As Photoredox Catalyst: Benzylation of Electron-Poor Olefins

作者：Montanaro Sara; Ravelli Davide; Merli Daniele; Fagnoni Maurizio^*; Albini Angelo

来源：Organic Letters, 2012, 14(16): 4218-4221.

DOI：10.1021/ol301900p

Excited tetrabutylammonium decatungstate (TBADT), known to activate a variety of compounds via hydrogen atom transfer (HAT), has now been applied as a photoredox catalyst for the effective oxidative cleavage of benzyl silanes and radical benzylation of reducible olefins occurring in isolated yields from poor to excellent.

• 出版日期2012-8-17