Dinitrogen extrusion from enoldiazo compounds under thermal conditions: synthesis of donor-acceptor cyclopropenes

作者:Deng, Yongming; Jing, Changcheng; Doyle, Michael P*
来源:Chemical communications, 2015, 51(65): 12924-12927.
DOI:10.1039/c5cc05006e

摘要

Donor-acceptor cyclopropenes are formed quantitatively or in high yield from enoldiazoacetates and enoldiazoacetamides under moderate thermal conditions. They are more versatile than their corresponding enoldiazocarbonyl compounds as carbene precursors.