Aziridine Nitrogen Inversion by Dynamic NMR: Activation Parameters in a Fused Bicyclic Structure

作者:de Loera Denisse; Liu Fang; Houk K N; Garcia Garibay Miguel A*
来源:Journal of Organic Chemistry, 2013, 78(22): 11623-11626.
DOI:10.1021/jo4022315

摘要

The nitrogen inversion of a N-phenyl aziridine fused to a succinimide ring is influenced by the presence of a phenyl ring in the succinimide moiety. The endo invertomer is favored, showing an unsymmetrical equilibrium in variable H-1 NMR studies.

  • 出版日期2013-11-15