Hybrid compounds of Schiff base Cu, Fe, Co complexes with molybdovanadophoric heteropolyacids: synthesis, characterization and their catalytic performance to hydroxylation of benzene with H2O2

作者：Chen, Lijuan^*; Xiang, Yujun; Feng, Tao

来源：Applied Organometallic Chemistry, 2012, 26(3): 108-113.

DOI：10.1002/aoc.1871

• heteropolyacid
• Schiff base
• hydrogen peroxide
• phenol
• hydroxylation
• synergistic effect

Hybrid compounds of molybdovanadophoric heteropolyacids and a Schiff base transition metal complex, M-saldmp or M-fpdmp (M=Fe(II), Co(II), Cu(II)), were successfully prepared and found to be effective catalysts for direct hydroxylation of benzene with H2O2. The synergistic effect between Schiff base metal complex and heteropolyacid plays an important role in the promotion of catalytic activity.

• 出版日期2012-3
• 单位湖南大学