Hydrothermal synthesis, structure and properties of copper-bipyridine complexes substituted mono-vacant Keggin arsenotungstate

作者：Zhao, Zhifeng; Zhou, Baibin^*; Su, Zhanhua; Ma, Huiyuan

来源：Solid State Sciences, 2010, 12(5): 803-807.

DOI：10.1016/j.solidstatesciences.2010.02.015

• Arsenotungstate
• Copper-bipyridine complexes
• Fluorescent property
• Electrochemistry

A new arsenotungstate, [H2AsW11O39][Cu-3(2,2'-bipy)(3)(H2O)(2)(OH)]center dot 2H(2)O (1) (2,2'-bipy = 2,2'-bipyridine), has been hydrothermally synthesized and structurally characterized by elemental analysis, IR, UV-Vis, TG and single-crystal X-ray diffraction. The compound 1 represents the first example of copper-bipyridine complexes substituted mono-vacant Keggin polyoxotungstate containing As-V. Compound 1 exhibits fluorescent property at room temperature. Furthermore, compound 1 has been used as a solid bulk-modifier to fabricate bulk-modified carbon paste electrodes (1-CPE) by direct mixing. The electrochemical behavior and electrocatalysis of 1-CPE have been studied in detail.

• 出版日期2010-5
• 单位哈尔滨学院; 哈尔滨师范大学; 黑龙江大学